I see some recipes call for you to add water to the fermentor (just before pitching yeast) to bring the contents up to 5 gallons. One recipe called for starting the boil with 6 gallons of water. Is one method better than the other assuming the water you add after the boil is purified or boiled and chilled.
One benefit I can think of is if you do it after the boil you could freeze a gallon of purified water and it would greatly aid in the cold break process.